Where does the other end of the cable end up?
I suspect (if I'm right about it being some old CATV/MATV system like Rediffusion) it'll end up outside on the soffit or window ledge somewhere and be tapped into a larger dristribution cable daisy chained between different houses.
The old rediffusion systems were live in Bristol (where I am) up until the late 90s, and I've heard that some of the old cabling is still used even today, so you might pick up something with a tester (providing of course that the other end is still connected!)
Remember that Rediffusion TV was different for each county/town. Some only had 4 channels (4 pair) some had 6 (like yours I believe) and others had as many as 22 pairs. Some used multiplex technologies, others had up to 6 co-ax cables running VHF signals etc... etc...
Mattylad, I take your point, the systems I've seen have never used that particular connector, but as I say, different regions had different tech.
I can't see how it would be a power connector personally... firstly the colours appear to all be in pairs (2 of each colour) and I can't see why a radio would need a 12 pole connector for power, and if they did why not just plug it in with a PSU, rather than go to the trouble of distributing a load of different DC/AC voltages about the place...?
Interesting stuff though, first things first though, where is the other end of that cable. Also where in the UK are you? Not all regions had cable tv installed, so that might be a clue.
Cheers
Dan