Hi Pat
Yes went with 6mm solid clear and worked out well.
Purlins are 200 x 50mm @ 600 ctrs - well over-sized but I was matching in with adjoining epdm roof which is t&g on 175 x 50.
There is flex in the sheet for sure but only when handling or fixing. When in place it looks just like glass.
For the top of the purlins you can see a grey one sided tape:
Scapa® 3507 PVC Single Sided Foam Tape 25 mm X 30 mtrs Thickness 2.5mm sourced online from Self Adhesive Supplies.
Nut sure if this is absolutely necessary but I felt it no harm to cushion the poly.
My pitch is 9 degrees so I was confident about my overlap detail as per photos.
Basically one sheet is 25mm higher that the other (2x1 batten on rafter) and overlap is circa 150mm.
Your pergola is probably close to flat to I suggest a proper glazing bar detail with gaskets and capping.
The one thing I did underestimate is the physical handling of the sheets and getting them up into place.
They are heavy and awkward, you will need a few pairs of hands and I see yours are bigger than mine !!
I had to make up a sort of a pulley / lift like this to get mine up
The sheet is easy to cut using correct blade, I had to notch mine around a pier. Drilling also easy too, again with correct bit.
Don't forget to oversize holes to allow for expansion.
For the fixings I went with these from ACCU:
https://www.accu.co.uk/en/sealing-raised-pozi-wood-screws/377517-SPRKSW-4-5-70-25-A2
Used the longer ones on upper sheet to go through extra batten and the 55mm for the lower sheet.
Just preferred the lower profile as opposed to the standard hex head cladding screw.
Kneeling or walking on sheets is probably unavoidable. I just used small sheets or ply placed on a blanket to avoid scraping the sheet.
I have walked on it since and followed lines of purlins and all fine.
Use neutral curing silicone for sealing fixings.
Come back if any more queries or send a pm