Conceptually I do not believe that it is a difficult task, but from a practical viewpoint I do not know what physical difficulties you would face when installing the new cables.
Does the second diagram above make sense to you? Do you look it and think "Ah, that's how it all works", and can you see what needs to be done? i.e. could you draw on a piece of paper the new wiring that you need to install?
If so, then the difficulties you will face are purely those of physical installation.
If not, then you will probably need to do a bit more reading, and looking at the real thing in your house, before you have a go. It isn't rocket science, but if you want the job done this weekend, and you currently don't have a clue what to do, then I fear you may struggle, and you might be better advised to get an electrician in.
But if you do want to learn, then those diagrams came from
here
There's also
this which describes adding a wall light with its own switch, so the equivalent to what you need to do.
This DIY-er's site is a good one:
here
And finally there are a number of useful books - I can't recommend any from personal experience, but the Collins DIY encyclopaedia and the Which? Book of Wiring and Lighting are frequently recommended by others.
Returning to your job, you will need to break into the lighting circuit at a particular point, and put in a 4-way junction box so that you can run a new cable down to a new switch (which could be completely new, or you could replace your existing 2-gang switch with a 3-gang). So the 4 terminals in the JB would be Live, Neutral and Earth, coming in and going out, with the switch cable connected to Live and the 4th terminal (and of course earth for the metal box), and the outside light connected to the 4th terminal, Neutral, and Earth if it has one. (if it doesn't, connect it anyway at the JB for protection, and at the light just make the wire safe somehow - don't cut it back in case someone needs it in the future. Same goes if you have a plastic box for the switch and don't actually need to earth it).
[
I don't know if you are allowed to use the terminals in an existing rose for a completely separate light and switch - maybe someone who knows the regs can advise on that]
If it isn't very obvious to you what you need to do, then I don't think you are ready yet to DIY.
You will need to lift floorboards to get access to the wiring, you will need to identify which cables are which (a multimeter or some voltage indicating device is almost essential), and you will probably need to chase a channel in the wall to take the new switch cable (in conduit or under capping), and sink a hole for the box if you are using a separate switch. If you use a 3-gang in place of the current 2-gang, count yourself
very lucky indeed if you are able to get the new switch cable down the same run as the existing ones.
And don't forget all the motherhood-and-apple-pie stuff about turning off the power, making sketches, labelling cables, all the earth wires should be properly sleeved in green/yellow, and the switched live should be marked with red tape or red sleeving.
And good luck!