Will be OK, but more than likely need to re-balance system afterwards.
How many are you adding? Be aware that main runs of pipework from boiler, usually 22mm, can only distribute so much heat. For the 22mm, it will be OK for approx 38,000BTU or 40KW. If the pipes that you are extending to the loft from existing rad circuits are already up to the limit, you may need to make changes.