Not really certain I understand what your question is, but to some extent your choice of type of insulation is driven by your build system, desired wall thickness, desire to reduce costs and desire to save the planet
How are you constructing your walls? Standard rick and block leaves full full cavity? Any reason why you're going for a highly technological (by comparison) floor and relatively standard walls?
When looking at any insulation, check the lambda value. This is a measure of how good an insulant it is. Wool is typically around 0.044 down to 0.032. Kingspan is 0.022, vacuum panels are as low as 0.07. This means a hundred mil of wool could be as insulating as 50mm of kingspan or 16mm of vacuum panels. Price for wool and kingspan is somewhat proportional, Vac panels are eye watering.
Incidentally, 100mm of wool isn't a lot, and isn't enough to get you to current regs standards on its own. For floors, if you're not having underfloor heating then there isn't much point going better than regs because warm air generally rises so you're not losing a huge amount of heat through your floor. Not so for walls and roofs, where here is plenty of sense in bettering the regs, particularly if you're building an entire house. As you're only doing an extension, the rest of the house could end up being something of a heat parasite, so there are sensible limits you should impose- for example, no point doubling your insulation spend to get from 0.15 walls to 0.1 walls, when you could take that money and put it towards extenally insulating the rest of the house
The other thing you want to keep a check on, is the quality of the build. No point spending thousands on kingspan if it's going to be poorly installed and end up with gaps through which cold air can get. Might as well stand the sheets up in the garden if hats he case. Passivhauses, houses that have no heating system because e amount of sunlight coming enough the windows is enough to offset the amount of heat the house loses on even the coldest days, don't necessarily have walls with incredibly low u values- they have to be 0.15 or better, but the big difference between a passivhaus and a house built to uk regs is he level of draughtproofing. A passivhaus is permitted to lose up to 0.6 times its volume per hour, whereas a U.K. Regs house may lose an amount around ten times that (it varies based on the house shape) before it fails an air test. Understandably, the biggest concern in a U.K. Regs house is draughts and holes in the structure leaking away your heat, not it passing through the walls, windows and roof