Cannot find any reason for rads heating up on return line during hot water call, Would fitting a non-return valve to return line be an acceptable solution.
It's normal to put nrv's in line when say 2 boilers are in parallel, but use an oversize one - ie for 28mm/1". I'd speak to Ariston first, I'd bet there's some route inside the boiler which is being taken. Have seen it before.
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