It's an old sunvic one, I'd gone to replace the stat as it was faulty, checked and there were 3 wires, live , switch live and neutral
How was the old stat faulty? Was the C/H partially working with the old stat, before the attempt at exchanging it for a new one?
And if, as
@stem has suggested, you have a switched neutral; then that's just asking for trouble IMO!
However, the 'N' Stem highlighted in the screenshot, is just named as 'link N' - having alphabetically followed on from 'loosen the screws M' - it doesnt represent 'Neutral' (although it could be a happy coincidence)!
I believe the connector block is designed for a volt-free switching stat, even though it appears to be switching neutral.
For reference I've come to just swop the stat and couldn't get a normal stat to work.
Which stat did you try and swap out?
If you did manage to short a live and neutral, there appear to be two fuses on the PCB - it may be worth checking those...
EDIT - I haven't found the exact model of your Sunvic thermostat, but most versions show these type of connections -
Where 1 is L, 3 is SL and 4 is N.
Your connections within the boiler appear to show 1 and 4 connected to the boilers external control connector block, with the switched live (grey wire), connected to another block, that we can't see any connections to.
If the stat really was working with these connections, the circuit may have been made through the accelerator heater!
If you do intend to connect a new stat, the safest way would be to run one cable to power the stat and a separate one, purely for the switching; connecting the external control connector block, to the stats volt-free contacts.
The reuse of the old stat and legacy wiring, has certainly caused me some confusion!
...Not to mention Biasi's use of brown and blue wires on a connector block that requires a link to operate!