Boiler stat failure on older boiler on open vented systems, if no overheat stat would lead to the water boiling and pumping over into the header tank. My neighbour had this problem 2 weeks ago and had to get it sorted, but I was thinking... why would this happen? I too have an older boiler and was just curious. How would the temperature get 100 degress and boil, as the switched live to the boiler would surely be cut by the cylinder or room thermostat before that could happen?? Just a thought? If anyone can explain this to me I'd be grateful to them.