That fitting isn't a 15mm/1/2", not sure what they are as I tried what your suggesting on a similar boiler with a long flexi tap connector.
Just buy a compression T piece 22/22/15-and a flexible tap connector(15mm x 3/4"/22mm), cut the compression T into the return, insert a few inch's of 15mm copper & use the tap connector to hook up to the external EV, this is alot faster & easier than messin about soldering.
Another temporary fix is to choose a small radiator that isnt used much, isolate & drain it, then simply open 1 of the valves & top up sytem pressure, ideally on the return to boiler side(the pipe that gets coldest last) and leave the other closed, this then works as an EV indefinitely.
Also some EV's will leak if not pressurised as the membrane slips and fails to provide a seal, the correct procedure to ensure your not swapping a faulty EV is to remove schraeder core using a special tool(cheap to buy)then put a bit of tubing onto it, now fill up system and see if the water eventually stops, this can be several litres, if the water stops replace schrader, drain boiler & leave drain open, try to pressurise EV(if its totally gone it wont hold any pressure), if this pressurises test the schraeder valve with a small amount of soapy water for leaking air, refill system and heat test. This is important to check as quite a few EV's will pass water if not pressurised as the membrane is the seal.