I seem to remember it is called the W Plan, in my homes in the main a radiator will stay warm for the time one takes a shower for, the exception was the fan assisted radiator.
As to Nest, I fitted because it has the thermostat hard wired to the heat link, so no worry with flat batteries, and I can control CH and DHW from the thermostat. However it claimed it connected to the MiHome Energenie TRV heads, and yes the same program on my phone can control both together, as I lift or lower the wall thermostat temperature the TRV head will also lift and lower to match.
However what I wanted was for the TRV to tell Nest when heat was required, it will not do that, even when setting a schedule on Nest, the TRV will not follow, only when one manually changes temperature with the TRV follow the Nest wall thermostat, which is also the wrong way around.
The USA version has the option of temperature sensors, but they will not work with UK version.
The geofencing you can only set the eco and comfort temperatures, there is no option to set the distance. So rather useless, it had a load of other smart options, like anti legionnaires, I had to turn them all off, and the geofencing caused the house to get cold when the local EE mast was damaged in the wind, so had to turn that off.
The auto working out a schedule relies on all doors always being either open or closed, have door open one day and closed the next and one gets a really weird schedule set up.
Lucky I am not using the OpenTherm option, so I have been able to set up another wall thermostat in parallel, that has cured the problem with Wizer and Nest Gen 3 in parallel, only the Nest does DHW, but considering how Nest worked for me, it could be it is turning off at inappropriate times.
I am sure Nest would well with open plan homes, and hot air systems, but with a 12 room house, with doors on every room, it was a failure. Only good point, it it can be controlled from my PC, and the battery should never go flat.