Thank you to all, but especially Dan_Robinson, Master of None & Slugbabydotcom.
You have indeed answered my two questions.
As you surmise, my current internal PV is knackered, i.e oozes water when the schrader valve is pressed : sorry I thought I intimated that.
The boiler is a Ideal Isar HE30, i.e. 30kW (don't tell be how bad they are, I know only too well, I have to buy it fixerators every three weeks, see I do know the technical terms for the devices in the system)
The current size of the EV in the boiler is not quoted, but I would assume around 8 litres, and yes it is infinately easier to put in an external PV as I would have to demolish half the external wall to free up the flue before the unit would come off the piping frame. I'm all for the easy option at present as I want to keep the idiot of thing going till the summer when I intend to have it replaced. (not with another un-ideal boiler)
The current volume of water in the system I estimate to be 120 litres and once I include the new pipework and radiators in my extension it will increase to 200 litres.
Multiplying the vol by the magic figure of .074 gives the size PV I need as 15 litres.
Toolstation, who I prefer to
Screwfix as they tend to have things in stock, do a 12 litre or an 18 litre so I would err on the side of caution and get an 18 litre.
and yes I am quite capable of plumbing in a PV. I was wiping lead joints long before some plumbers could hold a tap spanner, still have the tallow ingrained in my hands to prove it!
And fear not everyone, I won't put an isolation valve in the pipe to the PV, afterall what's wrong with a freezing kit if I need to replace it in the future!
Wow, that was a lot of words!
Cheers, Dave