Jtbrown, good evening.
It appears that your door is situated within a Georgian / Victorian property??
If so then that door stop will be a [so called] planted door stop, meaning that the door stop that you need to reduce inwidth has bee nailed on to the door frame?
Can I suggest you very, very carefully using a sharp wood chisel very, very gently prize off the door stop, you can then cut to the width you need.
Can I also suggest that you cut the paint between the door stop and the door frame using a new sharp Stanley knife.
I think that your idea of a Dremel could be very difficult to control and get a true straight line which you will find acceptable??
Ken.