NOt quite, no!
There should be no voltage on the orange wires when there's no call for heat. If you disconnect them and put your meter across them , you should see between 25 and 40 volts AC when there is a call for heat. With the wires on the solenoid coil that voltage should be between 16 & 25VAC.
If the voltage is "killed" by the solenoid then it has shorted. If the volts aren't getting there look on the transformer.
Having looked it up it's pin C on the transformer , which is also connected to pin 3 on the combined thermostat and pump overrun switch, and pin D in the transformer which goes straight to the solenoid. The other orange wire (they're all orange) goes from pin 6 on the switch to the other pin on the solenoid. When the thermostat clicks it connects pins 3 and 6. Draw it - it'll make sense then!
If you're not seeing any volts at all look for mains across the transformer inputs, terminal block 10(Neutral, blue) and 12(Switched Live, Brown).
Hope that lets you sort it.
Transformer's about £50, Thermostat depends which model, may be £80 ish.
These boilers tend to die of leaking heat exchangers, by the way.