My Heat Slave all controls are external and DHW is thermosyphon with no valve for DHW only valves for central heating zones together with two pumps.
So what is needed is more information about the system, I considered using a thermostat on the DHW with a motorised valve but was advised against it, seems there are many versions of heat slave and mine is rather an early version with no cool down, so should either be C plan or Y plan, but latter versions changed.
I had a similar problem with my daughters Y Plan gas boiler, turned out to be micro switch in mid position three port valve, could not get micro switch so swapped whole valve. However latching the three port valve to bleed position and it worked, but in summer the radiators got warm. Seems that had been done, and my son-in-law had caught the lever when tiding up, which stopped it working.