bell824 - No, I don't think I missed the point of it at all. It said, essentially, GAS! - leave it to the professionals. So, reasonably enough, I referred you to the announcement at the head of the P&CH Forum and made clear that I intended only to work on the water side of things.
But I am grateful for your second post, since it explains rather a lot about the familiar protestations of those with vested interests - I take it that you're a professional.
About forty years ago, I designed and installed an open vented gas central heating system. In those days, there was little in the way of legal obligations placed on us amateurs. Of course, I wouldn't have dreamt of doing any such thing without getting the design OKd, the pipework and wiring checked and the commissioning undertaken by a professional heating engineer. It saved me quite a bit of money. And, since then, I've tried to take an intelligent interest in such matters, finding Tolley's particularly useful concerning gas installation, not that I've thought of doing any since that first attempt, so complex have devices become, so endless the legislation and so threatening the penalties.
In all those pages, I cannot recall the definition of a combustion chamber ever being quite so extravagantly extended as to include an unsealed boiler casing! Now, it is true that Vaillant recognise the difference in the %age of CO2 present according to whether the front casing is on or off the boiler, but this difference is as little as 0.2%, while the tolerance allowed for both eventualities is plus or minus 1%! Even so, nothing in Vaillant literature, Tolley's or common sense suggests that the air inside the cabinet, completely "unsealed" from that in the kitchen (and what about all those other leaky holes in the bottom plate, through which pipes pass?) constitutes a "combustion chamber".
Similarly, to claim that the O ring around the seat of the PVR is to provide a gas seal, rather than the stunningly obvious water seal it is, seems, pardon me, arrant nonsense.
I'm not really interested in engaging with those who feel deeply threatened by the slightest suggestion that a water side component replacement is a serious breach of the regulations. As I said, this is my first combi boiler and I had wondered, in all innocence, if anybody could tell me if I'd got it right (as above) or not. Any takers?