Hornet:
Despite the fact that it's quite unnecessary, I've been using a corrosion inhibitor in my heating water for about 15 years now.
The chemical most commonly used here is potassium nitrite.
Open your phone directory to "Water Treatment" or look on the internet for Industrial Water Treatment. Probably the biggest company in this business is Drew Chemical, so if there's a Drew Chemical office in your area, you can probably buy some potassium nitrite from them.
How to inject it into your heating system?
Both the cold water supply for your washing machine and your boiler drain valve will probably have a hose thread on them.
Wrap a garden hose around the inside diameter of a 5 gallon pail and reach into the bottom of the pail and pull out the bottom of the hose and stuff a funnel in that end. Now, pour your potassium nitrite into the funnel so that the hose actually fills from the bottom so you don't get any air bubbles in the hose. Now connect one end of that hose to the boiler drain valve and the other to the cold water supply pipe to your washing machine.
Open the boiler drain valve.
Open the washer cold water supply valve, and inject the corrosion inhibitor into your heating system with the water supply pressure.
Close the boiler drain valve. Close the cold water supply valve to the washer.
Allow the chemical to circulate in your system for a few days, and then check the concentration of corrosion inhibitor by testing it's pH. The concentration will be effective as long as the water is sufficiently alkaline.
But, the only time you really should use a corrosion inhibitor in your heating water is if you're draining the water often and replacing it with fresh water. Why do you feel you need to use a corrosion inhibitor in your water?
Also, it occurs to me that I can do it the way I described because my heating system is much bigger than you'd find in a typical house. In a house, injecting water using the cold water supply pressure is a bit risky because the volume of the system is so much smaller that you could over pressure it and pop the pressure relief valve on your boiler. In that case, you might be best off just draining your system down a bit, removing an air vent from the highest elevation radiator in your house, pouring some corrosion inhibitor in, adding water to the system and bleeding off the radiators until water starts to come out, then turning on the circulating pump to mix the chemical into your heating water.