I would suggest you use a builder for the steels and overall structure.
LABC rules for energy, materials, structure etc are quite complex and although you may well have the DIY skills could you:-
Provide structual calcs for loads
Design RSJ sizes and fit them
Work to Building regs parts A, B, C etc...
Last year I did my loft and as a engineer worked this:-
Planner / drawings and permission process- Via skilled person £1200
Steels, cheeks, roof, dormer, floor- Via builder £14k
Rest I did myself:-
Stud work, lagging, plumbing, electrics, internal fit, even 40sq m of Code 4 lead cladding for dormer face, cheeks and valleys.
In the end it was 12 weeks of my time and £30k. Silly really since I could have been earning and the builder quoted £35k which would have worked out cheaper