perhaps this explains it? perhaps not?
Extract from another forum,
Guest_solidspin 27th April 2005 - 03:05 PM
I think I can comment on this, since I sit underneath a supercon magnet all the time!
Why hasn't anyone mentioned the source of magnetism on a macroscopic level yet? Great natural magnets are so because they're very often high-spin d-orbital elements (Fe, Co, Ni) and all their spins in these d-orbitals are unpaired and parallel. They have what's called a permanent magnetic moment, because their spins (their magnetic moments) always sit there like that.
HOWEVER, a permanent magnet CAN temporarily lose its moment if you crank up the temp beyond what's called the Neel temp. for that material. What's interesting is that when the electrons settle back down from the higher, thermally induced excited states, they go back to their parallel magnetic moment state.
Oxygen (O2) is paramagnetic, for example, because of its 2 unpaired electrons in what chemists call a "pi-antibonding orbital" - whatever - the point is that the unpaired electrons are randomly oriented magnetic moments, since there's no solid crystal lattice or fixed orientation (it's a gas gas gas!). So you can make oxygen's electrons line up in a parallel state if you apply a field to them (it's old school but its called a Guoy balance).
I just gave a talk on SMMs or single molecular magnets. Just like a paperclip is not magnetic but can be induced to have a magnetic moment (like we all did to mom's paperclips with refrigerator magnets), a new class of funky molecules (some as large as a freakin' protein) only 1 molecule big can be induced to have a long magnetization (like over 40 minutes - that's sweet). Even cooler, and I think STe or the1physicist mentioned this, its rare but DEFINITELY possible to see macroscopic observables of quantum mechanical phenomena. These SMMs demagnetize or relax in a stepwise fashion (not like the classical hysteresis curve, which is analog), corresponding to tunneling of magnetization to antiparallel spin states. Totally cool!
The supercon magnets are niobium tin (YBCO is great too, but it's a ceramic and therefore not malleable). It's just Faraday's law applied to a Niobium Tin (in my case) metal, which as the1physicist will agree is a free-electron gas lining up in Foch space.