Muggles, I'm confused.
The title of this topic is 'Old boiler not firing up'...
Prior to changing the Thermocouple, was the Pilot light still on? because there's a possibility you didn't need to change it.
I'm also beginning to think you changed the pilot light yourself?
Did this, obviously, involve you disconnecting the Gas Valve and Burner?
(I'm beyond worrying about any Regulations being broken, or Gas Leaks being left behind for that matter, so don't worry about those.)
The reason I ask is, as is often the case, I believe you may well have disconnected the power supply to the Gas Valve and/or user controls.
A few checks you can carry out before calling another RGI, as the 'plumber' you so willingly trusted has let you down;
Turn off the Pilot light, wait a few minutes, and re-light. Once a flame has been established, do not twist the push-button, but pull it towards you, so it is fully up from its seating.
- had you been a RGI you would understand the mechanism of the valve, and understand it is possible the rod could be stuck closed.
Check you have turned the power back on to the appliance.
- Is it connected to a fused spur? did you remove the fuse? has the MCB clicked off?
Check your user controls are all switched to the correct positions. Do you have a Room-Stat and is it switched ON? are the controls on the front of the appliance turned to MAX.?
I am trying to establish that everything else isn't working before I recommend you contact another RGI to attend and confirm the solenoid, before purchasing a new one.
It does 'seem' like it is possibly the solenoid, which I believe can be changed without needing an entire new valve?
But, I've never been to your property, nor have I ever seen your appliance(s), so I wouldn't like to say I am certain.
I hope I've helped, good luck!