With the area looking so dark, is it possible that the caulk wasn't/ isn't dry?
I know they say paintable in 1 hour, but if it is applied in thicker than the recommended beads it can take a lot longer to be dry enough to accept paint.
If it is dry, then the oil based undercoat is usually a good option.
I thought this myself before I painted - the caulk tube gives no indication of drying time. I actually left it three days before painting (mainly because of work, not because I was being over-cautious!) so it really must have been dry.
I'll try the suggestion of an oil-based undercoat.
Sorry, I jumped to an assumption - but that really does look like silicon that's been overpainted and not a paintable caulk.
I'm thinking faulty caulk - 3 days should be plenty, especially in the warm weather we have now, and it shouldn't need an oil undercoat - although certainly worth a try now you have the problem.
That Soudal stuff is absolute rubbish. I bought some after being horrified at what B&Q were charging for more well known makes (£6.50 for a tube of calk) when I got stuck one Sunday afternoon.
It doesn't like being painted and looks awful, almost translucent, if left.
Do yourself a favour and get some Everbuild 1hr caulk. Never fails and cheap as chips....
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