Ah right, so something like this?
So would it look something like the following:
Straight female valve onto copper pipe > extension piece > onto 90 degree valve > extension piece > onto TRV.
Almost...
Coupler straight onto bent female iron (lose nut and olive from bent iron).
Then from bent iron use the extension piece straight into the rad valve.
"if" the coupler, upstream of bent iron, gives you the projection you need from the wall!