When you call for hot water by turning on the tap your boiler acts like an instantaneous water heater and the water is heated as it passes. Too slow a flow here or excess scale as suggested by Tony is the most likely cause.
However because this is a combi there is also CH water in the heat exchanger as well. If this remains static it will kettle. So the pump runs and pumps the water through the HE back through the diverter valve, through a bypass and back to the pump.
[There is no secondary HE on this model ... CH and DHW all goes through the Heat exchanger in seperate but adjacent pipes]
Any reduced flow in this circuit would cause kettling so your diverter valve is a very likely place for a blockage. Pump and HE are suspect too.
A few months ago I powerflushed a system prior to renewing one of these boilers that had been a victim of bad installation not to mention abuse and neglect. It too was kettling badly. What I found during a post mortem was that the top inlet to the diverter valve was full of crud and I mean full of it. There were pieces of rust in there about 5mm in diameter.
Too much gas getting through is another possible cause of kettling. I know this should all be Corgi work but checking and adjusting the gas pressure should not be done by DIYers.
How you tackle it is up to you but in your shoes I would go straight for the diverter valve then check the pump. HE is unlikely but not to be ruled out. Then stick in a new Ch thermistor. A total cost of half a bucket of sweat
plus about a tenner for the thermistor which is considered to be a 'service item' for most Ravenheats.
After that get a Corgi guy to check burner pressure or just use a plain old FBH