First of all the nomenclature in the lid is for a single heating zone, so not all is applicable to your system.
The actual wiring is a bit of a rats nest....and difficult to see clearly what goes where. However there are two motorised valves controlling your two heating zones (and it looks like a 3rd motorisde valve for the hot water).
If you can identify the black cable coming from one of the heating motorised valves, then the brown wire from that, will likely be connected to one of the wires going to its room thermostat. Once you have identified the suspect wire, the other wire of course will be in the same sheath. I normally disconnect the suspect cable at both ends and then test it with a multimeter to make sure that it does indeed go to the room thermostat.
The process can then be repeated for the other room thermostat and its associated motorised valve.
Having said the above, there is the important matter with regard to the existing time control for your heating:
1. Do the existing room thermostats include time control. (i.e. are they programable thermostats that allow you to set both time and temperature) or...
2. Only thermostats and there is there separate time control elsewhere?
In the case of 1. the wiring centre will need major rewiring to connect the Drayton wiser to it. In the case of 2. Depending on its current configuration, you may be able to replace the existing time control with a 3 channel Wiser, then again if you don't have an existing 3 channel programmer some additional wiring and modification will still be required. This is often far more complicated that expected. You can read a previous thread about it:
https://www.diynot.com/diy/threads/help-with-drayton-wiser-install.513829/