It's not as straightforward as changing a light fitting. You now have two devices, a programmer and a thermostat and are replacing them with a single combined device. I'l explain how it's done and they you can decide if you are competent or not.
The Nest Heat link replaces the ST9100C which has the following wiring connections:
The wires from the ST9100C then go to the new Heat link terminals that have the same function.
ST N = Nest N
ST L = Nest L
ST 4 = Nest 3 heating call for heat
Link Nest L and 2 heating common
Then the BDR 91 needs to be decommissioned. It's wiring is:
The easiest way is to leave the BDR91 wired in and add a wire link between terminals A & B. This will take it out of action, but it will still be powered up and not doing anything.
Another, better option, is to remove the BDR 91 receiver and replace it with a junction box. Put the N and L wires in separate terminals so that they are isolated, and then the wires that came from A and B are connected together in another terminal to complete the circuit.
Alternatively, the best option, the BDR91 and its cable can be removed completely, and the link made inside the wiring centre instead. The terminals where the wires that went to A and B have been removed from are simply connected together.
Finally, the Nest thermostat can be powered via a plug in power supply, or alternatively by connecting it to the 12v terminals T1 and T2 at the Heat link.