I’m assuming the waste pipe goes through this hole & you want to fill the gap between the outside of the pipe & the wall! If he’s cut the hole properly with a core drill, the pipe should be a fairly snug fit; if so, I would just run a bead of silicone around it, outside & inside. If the pipe is a loose fit, use ordinary sand/cement mortar; make it flush with the brickwork on the outside but on the inside, keep it just below the surrounding plaster & finish it off with finishing plaster or even DIY filler if it’s not too large.
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