Unless somebody has seriously mis-wired your light fitting, Plugwash has correctly identified the functions of the wires in it. Here's the extra bit of information you need:
1) The earth terminal will be obvious and will never be live.
2) The terminal with three red wires in it will always be live whether the switch is on or not.
3) The terminal with two black wires and one old light wire (if still present) will never be live. It's the neutral line.
4) The terminal with the single black wire and the the other old light wire will be live only when the switch is on but there's a catch here. Because of capacitive coupling across the switch cable, most meters will show some voltage on this terminal if there is no light fitted. Neon screwdrivers will also glow but not as brightly as they do on the live terminal.
You will see that you need some means of checking for live terminals, namely a meter or a neon driver - and I mean a proper mains rated neon driver with an insulated blade, not some cheap piece of junk off a market stall.
And since you're new to electrics, here's a some valuable advice for working on live circuits:
1) Don't do it unless you can't avoid it, as in this case.
2) Wear rubber soled shoes.
3) Always be aware of what your other hand is doing. Holding onto earthed metal with one hand while you prod around a live circuit with the other is a really bad idea. The best place to put it is in your pocket.
Perhaps I've put you off the whole measurement business. In that case try this. Isolate the circuit at the fuse box and connect a simple, two wire bulb holder between the single black wire (switched live) and the paired black wires (neutral). Put a bulb in it then switch on at the fuse box. If the wall switch controls this light correctly then you have the right pair of terminals for your new lights. Nothing nasty can happen, even with the most diabolically mis-wired circuit, though you might get some strange effects, like the light won't come on/go off or it comes on dim and so do some others. If anything like this happens I suggest you get an expert in to sort the whole mess out.
Assuming that the test goes well, connect the brown wire(s) of your new lights to the switched live terminal (single black remember), blue to neutral and green/yellow to earth. Needless to say you do all this with power off.