Supermatt "can" causes problems further down the line.
Many years ago I used it to obliterate a dark pink vinyl silk bathroom. I then applied Dulux Trade waterbased eggshell over it. Within 2 weeks it crazed. I rang Dulux and the woman's response was "well it would".
In the decorating world it ranks as one of the most inappropriately used paints. As JohnD said, it is designed for new plaster- specifically for new plaster that hasn't completely dried out. Many decorators use it on perfectly dried plaster because the extra matt finish compensates for flaws in the new plaster and allows them to lower the quality of paint application.
It has a very low acrylic/latex content which makes it impossible to wipe clean. Effectively it is an inferior quality paint.
That said, it will adhere to the existing matt paint and will only potentially be a problem if you decide to paint over it with a shinier finish.
Dulux do sell Ultra Matt paint that is even more matt- they market it as having "anti-reflective technology". I have used it a few times. It is the only Dulux emulsion that I have used where you can touch it in and not see any halo effect. I have, and would only use it on ceilings. Stoopidly expensive and doesn't obliterate darks marks very well though.
Additionally they have Flat Matt- but I haven't used that. I did speak to another decorator who told me that whilst using it he had to stop half way through a ceiling and could not see any evidence of where he picked up later.
TL
R? Supamatt should be ok (so long as the room is not subject to moisture).