I sussed out the problem with the UFH. 2 zone valves were crossed over so increasing demand for heat in the hall was simply heating the kitchen!
Flushing was actually pretty easy and I did get a little bit of debris out which must have been in there since new.
I am sure that either the original installer had no clue or the previous owners played with it as this was a simple mistake.
The mixer valve being the wrong way around was a bit harder to spot but that is another story!
I am having the manifold replaced next week with an Uponor TM version which will give me the benefit of ease of balancing and also get rid of a leak I found (very small hair line crack in one of the current balancing ports).
I have spoken to Uponor who recommended this manifold to me. They have said to heat the pipes with a hair dryer before removing the olives from the pex pipe. Am I right in thinking this is to prevent damage? I did read that pex will return to original shape after heating?
Obviously I am a bit worried about the swap and I don't think I can afford to lose any length of pipe due to it only being 25cm from floor level already on the return fittings.
New connections do not use an olive. Connections have been redesigned and incorporate it in them which is clever.
Any tips for removal of old olives to avoid damage would be greatly received and I can pass them on to the heating and plumbing engineer next week