There is dissolved oxygen in water which comes out of solution when the water is heated. With an unvented system this disperses up the open vent pipe; it can get sucked into the inlet of a shower pump and cause problems, hence the need for the Warix, Surrey or whatever flange to draw hot water away from the open vent and the air bubbles.
With an unvented system, there's no vent (No s**t, Sherlock!) so the air comes out of the taps with the water. SFAIK there are no automatic air vents that are suitable for use with DHW. You may be getting more air now because the cold water is colder and can carry more dissolved oxygen (I think) or the supplier may be taking more water from a source with more dissolved oxygen (winter, high reservoir levels, so less borehole water used?). The temperature of the stored water is too hot, it should be 140 degF, 60 degC. Have you checked it with an accurate thermometer?
It could be is hydrogen from galvanic corrosion or electrolysis, but the volume of gas sounds far too much. Does the cylinder have a sacrificial anode and has it been replaced? Anodes were used on steel cylinders. When the sacrificial anode has been corroded, you then get a sacrificial steel cylinder. If there was an anode and it's gone, plan on replacing the cylinder before it splits.
Check whether the immersion heater has a leak to earth. Turn it off if it's also heated by a boiler and see if there's any change.