There is no need to disturb the wiring centre. They tend to be wired differently from installation to installation, depending upon the personal preferences of the installer and the layout of the various components in your home, so it's difficult to give advice about that over a forum and not being physically present too inspect it. So, I would suggest that you put everything back as it was and once you have confirmed that it's working, then proceed as below:
The LP522 wiring terminals are thus:
The existing wires are simply moved from the terminals of the LP522 to the terminals of the Nest Heatlink that have the same function. Don't worry if there are some terminals that do not have wires connected to them, if your system doesn't need them now, you won't need them with the Nest.
So:
LP522 N = Heatlink N
LP522 L = Heatlink L
LP522 1 HW off = Heatlink 4 Hot Water Satisfied
LP522 2 CH off = Heatlink 1 Heating Satisfied
LP522 3 HW on = Heatlink 6 Hot Water Call for Heat
LP522 4 CH on = Heatlink 3 Heating Call for Heat
The Heatlink common terminals (2 & 5) need to be linked to Heatlink L
The Nest Thermostat can be powered by wiring it to Heatlink T1 & T2 terminals, or alternatively by using a separate plug in 12V power supply for it.
If you don't have an existing wired room thermostat, that's it job done. If you do have an existing wired room thermostat it can't simply be disconnected as this would leave the heating wiring 'open circuit' and it would not operate. So you can:
1. Leave the existing room thermostat in place and set it to its maximum setting and leave it there, this will prevent it overriding the Nest. Or,
2. Find the origin of the thermostat cable. Note where the wires are connected and disconnect the cable. Then link the terminals where the two ‘live’ switching wires came from together. (This will probably be in the wiring centre) The Neutral, if present is simply disconnected. Or,
3. Remove the existing thermostat and replace it with a junction box, connect the two ‘live’ switching wires together and isolate the neutral (if there is one). Or,
4. Leave the existing room thermostat in place and join the ‘live’ switching wires together in a separate connector that you can tuck away in the corner of it.