Just to confuse the original poster further with more extraneous observations;
The hex in the photo could do with a service, all boilers need one annually stainless or aluminium.
The Atag has many more tubes of a far smaller bore than the French one mentioned, two narrow headers, meters of thin gasket and over 140 welds to boot.
A village hall maybe intermittent usage so prolonged running of the boiler to offset the poorer conductivity of stainless with weather compensation and OpenTherm may not be the way to go. If the heaters are radiators then fast high temp heat up ali would be a good bet run hot with no oxides through condensing.
I liked the point about the traditional copper fabricated exchanger with recuperator and variable fan speed linked to gas valve modureg but not premix - the Synergy and Syntesi were both the old Band A though not without faults like any boiler.
Anything that separates the combustion products from the system water will not help conductivity but with a factor of 13 times better thin wall ali has a bit of a head start over stainless and servicing properly maintains that advantage.
I'd say looking at the original question again and bearing the above in mind something one piece, no joints, no welds, extruded not cast, large bore, thin wall, low mass, high conductivity, long warranty, retarded flue flow in place of the recuperator and easy front servicing for the lazy service engineer would be something to consider.