Hi All
Thanks everyone for your help - I seem to be making progress but now I think I have another problem.
Done so far: Replaced all seals/gaskets in the diverter valve -> now the leak which was allowing water into the motorised valve appears to be fixed
As said here - couldn't find a 14mm long reach socket so had to leave the original nut in place.
Motorised valve is knackered though - terminals inside are corroded and it looked like it had arced. This also blew the 2amp fuse on the circuit board (well - that's all I can put the blown fuse down to).
Thought I'd try the valve again anyway, so cleaned it up, replaced the fuse and put the valve back together and re-fitted. Sure enough I get CH working but when I request hot water the valve doesn't turn and divert so no HW. If I take the valve apart and manually turn then I get the reverse - HW but no CH.
I've ordered a new motorised valve which will arrive tomorrow.
What I'm seeing now though is if I leave the valve in the CH position and run the boiler in CH mode, the manual timer clock doesn't seem to work anymore - it turns but doesn't switch off the CH when it should. I've also tried the timer in the 0 position and the external room thermostat turned right down but the boiler just seems to run constantly - heating the water to the required CH temp then turning off the burner then re-igniting and heating etc. The pressure seems OK (i.e. above 1.2 bar when off, dropping to 1 bar when initially turned on then rising to 1.2 ish bar when the waters been heated and the CH is flowing). Having said that, I've just turned the selector switch to off and the pressure gauge is now resting at 1.4 bar. I'm assuming this is because there's hot water in the system.
Do you think replacing the dodgy motorised valve with the new one will make the boiler behave normally again or could something else have broken? If I need to re-pressurise the expansion chamber how do I do that? I mention this because I've also noticed some water has been sent through the prv which I've never noticed before. I've just run the boiler now though in CH mode for 30 mins and haven't noticed anymore water coming out. The manual timer used to work fine so unless its broken now I can't think what else could be wrong.