Take it this house is new to you?
First one- lag the tanks and pipework in the loft and they'll be fine. (don't lag under the tanks tho)
2nd- hot water. If flow rate and pressure are OK on the existing setup then leave it alone. Any particular reason for not wanting hot water on a timer- again if the cylinder is well insulated then running costs are quite low. Megaflow would need heat from somewhere (timer) and they get a mixed press...also (like combis) they rely on good mains pressure and delivery rate so check that before you do anything
Pipework rads etc- if they work and are where you want them then leave them be, if you don't like them then change them
3 tanks- are all the cold taps off the rising main? (Find a friend, get him/her to go round the house turning taps on and off while you lurk in the loft watching which tank level drops when). Small tank should be F & E for the heating, 1 large tank hot water header, 2nd large tank poss cold water header, poss additional hot water.
Service valves on the tank supplies- might be non-existent, might be at the tank, might be in the airing cupboard. I've always fitted them in the airing cupboard for ease of access. You may find service/isolation valves on the tank outputs (for the hot and cold anyway, not on the F & E)- these are handy, they allow you to strip a tap without draining the header tank/hot water cylinder. If you have a service valve on the supply to F & E make it tamper resistant (if that one runs dry it could cause problems).
What size is your 'microbore'- 8mm, 10mm, 12mm? No reason any of it shouldn't last 50 years (inhibitor added), depending on water hardness in your area the smaller bore might be more prone to furring up (though smaller bore = higher water velocity for given heat transfer so may not be a problem). I've not used much microbore, odd bits of 12mm to get through convoluted routes & the oldest bit is now 28 and still works.
As suggested, if the system is clean and working then there shouldn't be an issue.
Some installers don't like it due to issues that can be found when flushing or will caveat it going from open vented to sealed.
You really need to get an installer in to have a good look and give you advice, being onsite they will be better placed to advise you. Try and get some local recommendations.
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