You can use a WiFi thermostat to do what you want if you choose one that has volt-free contacts, or use its output to energise an external relay. Simply ask it to supply a very high temperature (say 30C) when you want it ON, and a low temp when you want it OFF.
There are WiFi switches available, I have a SONOFF basic switche, which can be configured/wired to command your override. They also do a WiFi and RF version so that you have the choice of operation by Smarty-pants phone or a key-fob when at home. Typical cost between £5 and £10 each.
Another solution could be the GSM switches commonly used for remote gate opening/door unlocking. They allow simple switching of a volt-free contact via either a text message or a (n unanswered) telephone call. These are good where no t'interweb is available, or indeed for resetting the modem/router in areas where the router needs to be reset frequently! Search for GSM switch, or CL1 switch, or variations upon these. Typically £25 each, plus a quid for a Pay As You Go SIM card.
Hope this helps,
MM