It's your use of "diverter valve" which is causing confusion. COmbis have them internally, no need for further mention, system boilers can have then added if you have an external HW cylinder...
COmbi size is determined by your HW requirement. IF you have adequate supply, AND a monster shower OR run a lot of baths OR want to supply more than one outlet simultaneously, then a 42kW combi is suitable.
On the heating side it would short-cylcle quite a bit, but that shouldn't cause problems.
Gas supply shouldn't be a problem either, as long as you have fat enough pipe doing it. You'll almost certainly need at least 28mm, depending on distance.
Worcs boiler reliable?? Not particularly, but the telephone customer service is good.
I've just taken out three worcs boilers, from one house, at under 4 years old. Their owner was fed up with repeated breakdowns. Two Vaillant 42s went back in.