I would "guess" it's the HW on(call) from cyl stat - I do agree it's a shambles though.It sure isn't wired properly, and looking at all the earth wires carrying a phase I think the best advice is get a sparky, to re-wire the lot.
Clue the boiler live. the pump live, and the orange should be connected, but what the green and yellow does is anyone's guess
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