Well after spending over £450 I've definitely learned the hard way that I need to get an engineer round who knows what they are doing and my DIY efforts are done. Spend so far; Pump £113, Pump valve £5, Plastic joint box £1,Fused spur box £4, Leak sealer £3.50, Inhibitor £8, 3a fuses £2, Fluke volt detector £23, Adjustable wrench £12, Wiring box £14,Gas engineer £140,Posting PCB back £7, Motororised valves x 2 £94
Ferrule crimper £23
For anybody seeing this post in future my original issue was almost certainly a boiler fault, I guessed at a pump change, then decided to tidy up the spur box as red neon light had failed ages ago, saw a cable joint close to chimney breast on the boiler cable run - a connector wrapped in a bit of electrical tape and so I replaced this with a plastic box- failed to tighten wires correctly and spotted today the blue wire had come loose. Non contact voltage tester showed the cable as "live" consistent with permanent live lit on PCB in boiler. BAXI fault chart suggesting "no LEDs lit" is for engineers not DIY as you only see all the LEDs after gas fire front removed. The no lights at all fault suggests a fuse and if not that then a PCB change will be needed. I bought a PCB and a 3a fuse thinking this would prevent engineer needing 2nd visit. The dreaded engineer - he was told of the DIY bits I'd attempted and diagnosed a fault upstairs. Posted the PCB back - thank goodness for distance selling rules. 1 M.V replaced which didn't resolve anything. Then bought crimpers and wiring box - clearly got 2 cables wrong way round, what an ass to think fat wire to big boiler and little wire was going to small room stat without being certain. Alerted to my stupidity when the 3a fuse went POP as I turned the programmer on to heat, I'm thinking this has also damaged the microswitch on M.V two as it was definitely working before this sorry saga. Swapped them round - and after good advice - to be absolutely certain took up all floor boards and ripped out paneling to follow the cable its whole distance. Baxi fault chart suggests that if switched live LED is not lit first check is for mains voltage between SL and L and if not to check wiring and controls.
So the blue wire in the joint on the cable to the boiler has now been corrected and when HW is on I can hear sparking - nothing is lighting. Not sure if the last engineer has turned anything else off in the boiler but I'm assuming this was the original fault. 2nd MV is on its way so I will fit that. For anybody that doesn't know any recommended trades people Which has a trusted trader scheme. Hindsight is wonderful. The good thing to come of this is that I've forced myself to use the multimeter. I'll probably do a final update when a gas engineer has been and confirmed what the real issue was. Hoping my electrical wiring stupidity hasn't also damaged the PCB but the fuse on that hasn't blown when the boiler is clearly trying to ignite, fingers crossed.
Thanks to everybody for their help on this.