Well sorry but as you said it has never been serviced, probably just needs re-charging correctly, should be checked at every service, to be fair though far too many lazy so called engineers dont check it and dont know how to properly re-charge an EV, if I was in your shoes I would get Worcester to properly servive the boiler, not someone who presses in the schraeder valve and you will get value for your money
If the vessel valve is blowing out water when you press the schraeder valve then it means the diaphram is torn inside. It needs replacing.