I'll be honest and say I only understand half of the above :
Yes, I get the bit about 25mm blue MDPE being the best for an unvented set up due to the higher volume it can pass (although I also understood that both a decent flow AND a decent pressure is needed, and there's no mention of the latter).
BUT, if I've got this right, you've said if there's only a 15mm incoming main, then stick to a combi --- however I thought it was well accepted that a respectable incoming pressure and flow was required for a combi to produce a decent hot water supply (ie it can't supply more than it's receiving). And if there's only a 15mm incoming main then how is that going to be any better for a combi than it is for an unvented?