Ideally you want to maximise the hot and cold flow everywhere you can. You would want the mains increased to at least 25mm from the outside mains to your internal stop tap. Then at least 22mm up to the unvented and then 22mm out from the unvented to as close to the outlets as possible.
To give you an idea, I have an ultrasteel 180L unvented, 3 bar dynamic @ > 30L/Min and I can run 3 Mira Atom thermostatic rain showers at the same time with no complaints.
Some of the Armaflex insulation is great, Kooltherm is another one from Kingspan, there are numerous makes that would do the job. As suggested, it's always best to box in too.
To give you an idea, I have an ultrasteel 180L unvented, 3 bar dynamic @ > 30L/Min and I can run 3 Mira Atom thermostatic rain showers at the same time with no complaints.
Some of the Armaflex insulation is great, Kooltherm is another one from Kingspan, there are numerous makes that would do the job. As suggested, it's always best to box in too.