Hi I have a 3 port valve it is situated next to hot tank when i switch from h/w to c/h I can hear it click the c/h pipe gets hot so do the feed pipes to the rads . the valve is danfoss
Good so it does not seem as though the valve is a problem. The manual venting lever on the valve will be loose to move as well confirming the motor has driven the ball away to open the CH port.
Other than making sure you don't have any air locks in the system it seems that despite using X800 it has not completely cleared your system. So you may need to go for a power flush.
Out of interest and possibly as HERTSDRAINAGE2010 was seeking to find out. When you used the X800 did it initially clear the system and everything get hot. Did you turn your pump to maximum? How long did you leave the X800 in the system for? When you flushed it out did you do it while the system was still hot, or did you do it cold?