I suggest you isolate the pump at the valves, and split it open using the allen screws.
Look into the hole in the centre of the impeller and check it is not full of detritous where it leads to the vanes. Bits of rust get lodged here and massively block flow, leading to poor circulation.
Especially if the system wasn't cleaned properly or you have a particularly crusty set of old rads.
Only once you have checked the circulation is it worth diving into the boiler.
Look into the hole in the centre of the impeller and check it is not full of detritous where it leads to the vanes. Bits of rust get lodged here and massively block flow, leading to poor circulation.
Especially if the system wasn't cleaned properly or you have a particularly crusty set of old rads.
Only once you have checked the circulation is it worth diving into the boiler.