Wow, so much stupid in one postPut a blending valve on the DHW draw off and store water at approx 80C. Normally the boiler cuts in when the cylinder is one third exhausted. Add a flow switch to the cold feed to the cylinder, so when DHW is drawn off the boiler cuts in immediately, combining the boiler output and energy in the cylinder. Simple, by fitting a blending valve and a flow switch.
Just by adding the blending valve will bring excellent results. Store the water as hot as possible, 80-85C. Adding the flow switch would be even better.
Unvented cylinder stats don't usually go above 65, much more than that and the safety overheat cutout will activate, so you'd have to swap it out for a non-approved type with no safety.
You're then bypassing the stat altogether with the flow switch, which is clearly unsafe. What happens if the switch jams on? The cylinder just gets hotter and hotter, potentially 90°C, or even hotter if it's an old boiler on with a dicky stat.
You're also using a huge amount of additional energy running the cylinder like this