One more time...While a having a Buffer for heating may well be a fine engineering idea, it is not worth doing here. The boiler is Band D but IMHO far from on its last legs yet. You simply need to get the system set up correctly and balanced. You may by all means combine the feed and vent to prevent air ingress and over pumping.
Oh and DD - Condensing is the last thing this boiler needs. But then you knew that already didn't you It won't short cycle if it is set up correctly; but it will cycle like all boilers do on a conventional system. Its called heat loss.
Oh and DD - Condensing is the last thing this boiler needs. But then you knew that already didn't you It won't short cycle if it is set up correctly; but it will cycle like all boilers do on a conventional system. Its called heat loss.