The problem could be your 3 way actuator.
In the rest position it caters for hot water only. In the mid position it caters for both hot water and central heating.In the final position it caters for central heating only.
You may find it functions OK in the mid position and you get some heating but as soon as the hot water cylinder is satisfied it is supposed to move to the final position and supply a live feed to the boiler through a micro switch. You need to establish if it works ok in mid positon, you may have to run a bit of hot water off or increase the cylinder stat. Feel at the pipes coming from the 3 way valve (not too near the valve) If the water is being shared then both pipes should be hot. If the pipe going to the radiators is cold(ish) it suggests the valve has not moved to mid position. If everything functions in mid positon you need to establish if the valve moves to the final position. You should be able to hear it move or see an indicator light. If it does move to the final positon you need to establish if the live supply to the boiler exists. You can verify if there is a voltage or not in the wiring terminal box on the terminal containing the 'orange' wire.
Do you know if the actuator head can be removed from the valve, if it can it makes it easier to check, you can see the actuator move according to the various demands.
In the rest position it caters for hot water only. In the mid position it caters for both hot water and central heating.In the final position it caters for central heating only.
You may find it functions OK in the mid position and you get some heating but as soon as the hot water cylinder is satisfied it is supposed to move to the final position and supply a live feed to the boiler through a micro switch. You need to establish if it works ok in mid positon, you may have to run a bit of hot water off or increase the cylinder stat. Feel at the pipes coming from the 3 way valve (not too near the valve) If the water is being shared then both pipes should be hot. If the pipe going to the radiators is cold(ish) it suggests the valve has not moved to mid position. If everything functions in mid positon you need to establish if the valve moves to the final position. You should be able to hear it move or see an indicator light. If it does move to the final positon you need to establish if the live supply to the boiler exists. You can verify if there is a voltage or not in the wiring terminal box on the terminal containing the 'orange' wire.
Do you know if the actuator head can be removed from the valve, if it can it makes it easier to check, you can see the actuator move according to the various demands.