For a 100A supply you are going to require 10.0mm² bonding conductors whether the supply type is TN-S or TN-C-S
544.1.1 Except where PME conditions apply, a main protective bonding conductor shall have a cross-sectional area not less than half the cross-sectional area required for the earthing conductor of the installation and not less than 6 mm². The cross sectional area need not exceed 25 mm² if the bonding conductor is of copper or a cross-sectional area affording equivalent conductance in other metals.
Except for highway power supplies and street furniture, where PME conditions apply the main protective bonding conductor shall be selected in accordance with the neutral conductor of the supply and Table 54.8.
Where an installation has more than one source of supply to which PME conditions apply, a main protective bonding conductor shall be selected according to the largest neutral conductor of the supply.
So for a TN-S supply, first we have to calculate the size of the earthing conductor.
This is calculated using Table 54.7
For this we need to know the cross-sectional area of the line conductor, which looking at Table 4D1A requires 25 mm² cable for a 100A supply.
Now back to Table 54.7
As the cross-sectional area of line conductor is greater than 16 mm² and less than or equal to 35 mm² the formula used to calculate the required size of the earthing conductor is
k1
---- x 16
k2
We get the value of k1 (the k value for the line conductor) from Table 43.1, which for a 70°C Thermoplastic insulated copper conductor k = 115
The value of k2 (the k value for the protective conductor) from Table 54.2, which for a for a 70°C Thermoplastic insulated copper conductor k = 143
By entering the figures into the equation,
115
----- x 16
143
= 0.8041958041 x 16
= 12.86 mm²
As the formula has produced a non-standard size, a conductor having the nearest larger standard cross-sectional area shall be used.
So, a 16 mm² main earth is required.
Now we have established the size of the main earth, we can go back to the first part of 544.1.1 (Except where PME conditions apply, a main protective bonding conductor shall have a cross-sectional area not less than half the cross-sectional area required for the earthing conductor of the installation)
Half of 16 mm² is 8 mm² which again is a non-standard size, so a conductor having the nearest larger standard cross-sectional area shall be used.
That is 10 mm²