The wall have already been insulated and the double glazing is quite new.
Yes, but are we talking of a piddling 50mm cavity insulation, and cheap poorly fitted double glazing (poorly fitted as not in line with the cavity insulation and with an uninsulated steel lintel)?
18c is a typical temperature for bedrooms, the humidity would have to reach 73% for it to condense on a 10c surface, but only about 55% for a 5c surface.
So it's either getting very humid in there or likely the windows are naff (or a bit of both).