empty a rad and dont bleed. and use that as a temporary expansion point.
If there is water coming out of the Schroeder valve, then the expansion vessel is £ucked.
probably just needs recharging with a foot pump. and yes water should be coming out of the flexi. also check the aav on the top of the boiler to the front left near the plate heat ex. usually these let by. more so if you retop the boiler, after its drained down.
When the expansion vessel was installed on your appliance and the system filled with water did water come out of the air filling valve if you pushed it in?
I said the Schraeder valve, not the flexi. If water comes out of where the air charge goes in, then the diaphragm / bladder has a hole.
The pressure relief pipe that goes outside is dry.
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