Yes, if (as is usually the case) the pan contains water-based things, then the contents will be at 100°C or so (and cannot be much hotter than that), but the outside of the pan will usually be much cooler. It so happens that I've just boiled a kettle on a hob. Whilst it was boiling, I was just about able to touch the outside for 2-3 seconds, suggesting a temp appreciably below 100°C.I'm not sure about that. Water boils at 100⁰C. The pan must be at or above 100⁰C to keep the water boiling.
Indeed, as I said, it's different if the pan contains something with a boiling point much higher than that of water.Also, frying pans get a lot hotter than 100⁰C, surely.
Kind Regards, John