Re-charging the vessel will force the water out of the vessel, as long as the system pressure has been released and a vent/drain is left open as the vessel is being charged up.
Any EV, whether it's large or not will fill up with water anyway when the system heats up and the water expands, that's the way it works. When the system is cold and under normal pressure, ~1bar, then the pre-charge pressure in the vessel pushes the water out of the EV and into the system, as the system runs and heats up the water expands, the pressure increases and forces water up into the vessel, as the air can be compressed, then it does absorbing that increase in pressure and stops the system from overpressurising.
If the EV is undersized, it means that the system water volume and pressure increase is greater than the vessel can absorb, the system pressure then rises to the point that the PRV may lift.
As suggested though, they should be doing it - oh and the EV pre-charge won't need to be up as high as 1.5 bar, no more than 1bar would normally be required.